Answer: B
In the diene, one terminal methyl is on the outside and one on the inside of the s-cis form, so after cycloaddition the two methyl groups end up on opposite faces of the ring (trans). The trans isomer is (3R,6R) or (3S,6S), chiral and formed as a racemate. The cis isomer would be meso and would come from the (E,E) diene.