JEE Main levelSingle correct optionDifficulty 2 of 3hc118
What is the minimum number of equivalents of NaNHX2 needed in liquid ammonia to convert 1,2-dibromopropane completely into sodium propynide, CHX3−C≡CX−NaX+?
A1
B2
C3
D4
Answer: C
Two equivalents bring about the two successive dehydrobrominations (CHX3CHBrCHX2Br to a bromopropene to propyne). The terminal alkyne is then acidic enough to be deprotonated by a third equivalent. Total = 3.