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JEE Main levelOne or more correct optionsDifficulty 2 of 3hc104

Which of the following can act as the diene component in a Diels-Alder reaction? Select all that apply.

  1. Acyclopenta-1,3-diene
  2. Bcyclohexa-1,3-diene
  3. Cbuta-1,3-diene
  4. Dpenta-1,4-diene

Answer: A, B, C

A Diels-Alder diene must be conjugated and able to adopt an s-cis conformation. Buta-1,3-diene can, and the cyclic 1,3-dienes are held s-cis. Penta-1,4-diene is an isolated diene with an carbon between the double bonds, so it cannot take part.
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