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Ozonolysis and oxidative cleavage
JEE Main level
Single correct option
Difficulty 2 of 3
hc045
Buta-1,3-diene,
CH
X
2
=
CH
−
CH
=
CH
X
2
, is subjected to ozonolysis with reductive work-up. The products are
A
ethanal only
B
methanal and ethanedial in the mole ratio 2 : 1
C
methanal and ethanal in the ratio 1 : 1
D
butanedial only
Answer: B
Both double bonds are cleaved. The terminal
CH
X
2
=
carbons give two
HCHO
, and the two central carbons form
OHC
−
CHO
(ethanedial). The ratio is 2 : 1.
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