Aryl halide reactivity and monochlorination product counts

13 questions on Aryl halide reactivity and monochlorination product counts from the Haloalkanes and Haloarenes chapter: 2 NEET level, 5 JEE Main, 6 JEE Advanced. Each one opens with its answer and solution.

• Compound shown does not react with aqueous NaOH at room temperature, unlike a typical alkyl chloride. The main reason is: NEET level, drawn structure
• How many different monochlorination products (constitutional isomers, ignoring stereoisomers) can the alkane shown form on free-radical chlorination? NEET level, drawn structure
• The compound shown is warmed with aqueous NaOH at about 368 K and the mixture is then acidified. Which structure is the organic product? JEE Main level, drawn structure
• Under conditions (aqueous NaOH, 443 K) in which the para-nitro isomer of the compound shown is hydrolysed, the compound shown: JEE Main level, drawn structure
• How many monochlorination products (constitutional isomers; ignore stereoisomers) can the alkane shown give on free-radical chlorination? JEE Main level, drawn structure
• Counting enantiomers as separate compounds, how many monochlorination products (all stereoisomers included) can the alkane shown give? JEE Main level, drawn structure
• The compound shown is treated with NaNH2 in liquid ammonia and reacts through benzyne intermediates. Considering every benzyne that can form by removal of a hyd... JEE Advanced level, drawn structure
• The compound shown is heated with aqueous NaOH at about 433 K and the mixture is then acidified. Which structure is the main organic product? JEE Main level, drawn structure
• The compound shown is stirred with aqueous NaOH at room temperature and the mixture is then acidified with dilute HCl. Which structure is the final organic prod... JEE Advanced level, drawn structure
• The compound shown reacts with aqueous NaOH on warming. Select all correct statements. JEE Advanced level, drawn structure
• Counting enantiomers as separate compounds, how many monochlorination products in total (all stereoisomers) can the alkane shown give? JEE Advanced level, drawn structure
• The alkane shown undergoes free-radical monochlorination. Counting enantiomers as separate compounds where relevant, select all correct statements. JEE Advanced level, drawn structure
• The compound shown is treated with NaNH2 in liquid ammonia. Select all correct statements. JEE Advanced level, drawn structure