JEE Advanced levelSingle correct optionDifficulty 3 of 3hx201
Methane (8.0 g, atomic masses C 12, H 1, Cl 35.5) is completely chlorinated to CClX4 with excess chlorine under UV light. The mass of ClX2 consumed is
A142 g
B71 g
C284 g
D35.5 g
Answer: A
CHX4+4ClX2CClX4+4HCl. Moles of methane =8.0/16=0.50. Moles of ClX2=4×0.50=2.0; mass =2.0×71=142 g.