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JEE Main levelSingle correct optionDifficulty 2 of 3hx157

The melting points of dichlorobenzenes are: 1,2-isomer , 1,3-isomer , 1,4-isomer . The high value for the 1,4-isomer is best explained by

  1. Aits higher dipole moment than the other two isomers
  2. Bits symmetrical shape, which packs better in the crystal lattice
  3. Cits larger molecular mass than the 1,2- and 1,3- isomers
  4. Dstronger hydrogen bonding between molecules

Answer: B

All three isomers have the same molar mass. The para isomer is the most symmetrical (zero dipole moment) and fits best into the crystal lattice, so more energy is needed to melt it. Its dipole moment is lower, not higher, and there is no hydrogen bonding.
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