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JEE Advanced levelSingle correct optionDifficulty 3 of 3hx088

Ethylmagnesium bromide is treated with ethanenitrile, , and then with to give . is warmed with and aqueous to give a yellow precipitate and a sodium salt . is

  1. Asodium butanoate
  2. Bsodium methanoate
  3. Csodium propanoate
  4. Dsodium ethanoate

Answer: C

Addition of the ethyl carbanion to gives an imine salt which hydrolyses to the ketone , butan-2-one. It has a group, so the iodoform reaction gives and the carboxylate of the remaining chain, . is sodium propanoate.
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