JEE Main levelSingle correct optionDifficulty 2 of 3hx082
CHX3CHX2MgBr reacts with ethylene oxide (oxirane), and the product is hydrolysed with HX3OX+. The product is
A2-methylpropan-1-ol
Bbutan-2-ol
Cpropan-1-ol
Dbutan-1-ol
Answer: D
The carbanion opens the strained epoxide ring by attacking a ring carbon, giving CHX3CHX2CHX2CHX2−OMgBr. Hydrolysis gives the primary alcohol with two more carbons than the Grignard alkyl group: CHX3CHX2CHX2CHX2OH.