MolSynapsequestion bank
MolSynapse / Question bank / Haloalkanes and Haloarenes / Organometallic reagents: Grignard and organolithium
JEE Main levelSingle correct optionDifficulty 2 of 3hx081

Which of the following halides cannot be converted directly into a stable Grignard reagent with in dry ether?

  1. A
  2. B
  3. C
  4. Dbromocyclohexane

Answer: C

A Grignard reagent reacts with any acidic proton. In 2-bromoethanol the carbanion formed would be protonated by the hydroxyl group of another molecule (or the same one), destroying it. The other halides have no active hydrogen.
Practice Haloalkanes and Haloarenes More on Organometallic reagents: Grignard and organolithium

More questions on Organometallic reagents: Grignard and organolithium