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JEE Main levelOne or more correct optionsDifficulty 2 of 3g3032

Select the cation(s) which cannot be converted into a more stable carbocation by any single 1,2-hydride or 1,2-methyl shift.

  1. A2-methylpropan-2-yl cation,
  2. B3-methylbutan-2-yl cation,
  3. C2,3-dimethylbutan-2-yl cation,
  4. D2,2-dimethylpropyl cation,

Answer: A, C

Tertiary cations (first two) can only shift to give a secondary or primary cation, so they stay. The 3-methylbutan-2-yl cation () gives a cation by a hydride shift, and the primary neopentyl cation gives a cation by a methyl shift.
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