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JEE Main levelOne or more correct optionsDifficulty 2 of 3g3030

Select the correct statement(s) about the tert-butyl cation .

  1. ANine C-H bonds can overlap with the empty orbital through hyperconjugation.
  2. BThe cationic carbon is hybridised and the skeleton is planar.
  3. CIt is paramagnetic because the cationic carbon has an unpaired electron.
  4. DIt is more stable than the isopropyl cation.

Answer: A, B, D

The cationic carbon has three sigma bonds, so it is and planar, with 9 alpha C-H bonds (). It has 6 electrons, all paired, so it is diamagnetic. Having more alkyl groups, it is more stable than .
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