JEE Main levelOne or more correct optionsDifficulty 2 of 3g3030
Select the correct statement(s) about the tert-butyl cation (CHX3)X3CX+.
ANine C-H bonds can overlap with the empty p orbital through hyperconjugation.
BThe cationic carbon is sp2 hybridised and the CX3CX+ skeleton is planar.
CIt is paramagnetic because the cationic carbon has an unpaired electron.
DIt is more stable than the isopropyl cation.
Answer: A, B, D
The cationic carbon has three sigma bonds, so it is sp2 and planar, with 9 alpha C-H bonds (3×3). It has 6 electrons, all paired, so it is diamagnetic. Having more alkyl groups, it is more stable than (CHX3)X2CHX+.