MolSynapsequestion bank
MolSynapse / Question bank / General Organic Chemistry III: Reaction Intermediates / Carbocations: formation, stability, rearrangements
JEE Main levelSingle correct optionDifficulty 2 of 3g3013

3-Methylbutan-2-yl cation, , rearranges by a single 1,2-shift to:

  1. A2,3-dimethylbutan-2-yl cation
  2. B3-methylbutyl cation (primary)
  3. C2-methylbutan-2-yl cation
  4. D2-methylbutyl cation (primary)

Answer: C

A hydride on the neighbouring tertiary carbon shifts to the cationic carbon. The positive charge moves to the tertiary carbon, giving (2-methylbutan-2-yl cation). The other options either are primary or have the wrong carbon count.
Practice General Organic Chemistry III: Reaction Intermediates More on Carbocations: formation, stability, rearrangements

More questions on Carbocations: formation, stability, rearrangements