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General Organic Chemistry I: Electronic Effects
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Aromaticity, antiaromaticity and Huckel rule
JEE Main level
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Difficulty 2 of 3
g1143
Which of the following are antiaromatic?
A
cyclobutadiene
B
cyclopropenyl anion (cycloprop-2-en-1-ide)
C
cyclopentadienyl cation (cyclopenta-2,4-dien-1-ylium)
D
cyclopentadienyl anion (cyclopenta-2,4-dien-1-ide)
Answer: A, B, C
Each of the first three is planar, cyclic and conjugated with 4 pi electrons (
4
n
with
n
=
1
), so each is antiaromatic. The cyclopentadienyl anion has 6 pi electrons and is aromatic.
Practice General Organic Chemistry I: Electronic Effects
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