JEE Main levelOne or more correct optionsDifficulty 2 of 3g1132
Which of the following statements about hyperconjugation are correct?
AIt requires at least one C-H bond on an sp3 carbon attached to a pi system or a cationic centre.
BThe ethyl cation CHX3CHX2X+ has 3 hyperconjugative structures.
CThe tert-butyl cation (CHX3)X3CX+ has 9 hyperconjugative structures.
DThe methyl cation CHX3X+ is stabilised by hyperconjugation.
Answer: A, B, C
Hyperconjugation needs alpha C-H bonds, so statement 1 is true. The number of structures equals the number of alpha hydrogens: 3 for CHX3CHX2X+ and 9 for (CHX3)X3CX+. CHX3X+ has no alpha carbon, so statement 4 is false.