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JEE Main levelSingle correct optionDifficulty 2 of 3g1084

In , which atom carries the greater partial positive charge among the two alkene carbons, and why?

  1. ABoth carry equal charge, since the bond is non-polar
  2. BThe terminal carbon, because of the +M effect of the group
  3. CThe carbon attached to , because of the -I effect of alone
  4. DThe terminal carbon (the carbon farther from ), because of the -M effect of the group

Answer: D

The group withdraws pi electrons through conjugation (-M): . This puts the positive charge on the terminal carbon. The inductive effect decays with distance, so it is not the main factor.
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