JEE Main levelSingle correct optionDifficulty 2 of 3g1084
In CHX2=CH−CHO, which atom carries the greater partial positive charge among the two alkene carbons, and why?
ABoth carry equal charge, since the C=C bond is non-polar
BThe terminal CHX2 carbon, because of the +M effect of the CHO group
CThe carbon attached to CHO, because of the -I effect of CHO alone
DThe terminal CHX2 carbon (the carbon farther from CHO), because of the -M effect of the CHO group
Answer: D
The CHO group withdraws pi electrons through conjugation (-M): CHX2=CH−CH=OX+X22+CHX2−CH=CH−OX−. This puts the positive charge on the terminal carbon. The inductive effect decays with distance, so it is not the main factor.