MolSynapsequestion bank
MolSynapse / Question bank / General Organic Chemistry I: Electronic Effects / Inductive effect
JEE Advanced levelSingle correct optionDifficulty 3 of 3g1027

Arrange in decreasing order of acid strength: (P) , (Q) , (R) .

  1. AP > Q > R
  2. BQ > R > P
  3. CR > P > Q
  4. DR > Q > P

Answer: D

The carbon attached to is sp, sp2 or sp3, and its electronegativity increases with s character. A more electronegative carbon withdraws electrons (-I) from the carboxylate more strongly. This gives propiolic (pKa 1.9) > acrylic (4.3) > propanoic acid (4.9).
Practice General Organic Chemistry I: Electronic Effects More on Inductive effect

More questions on Inductive effect