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JEE Advanced levelSingle correct optionDifficulty 3 of 3g1026

Arrange the carbanions in decreasing order of stability: (P) , (Q) , (R) , (S) .

  1. AP > R > Q > S
  2. BS > R > Q > P
  3. CQ > P > R > S
  4. DP > Q > R > S

Answer: D

The lone pair of a carbanion is more stable in an orbital with greater s character (sp > sp2 > sp3) because the carbon is effectively more electronegative. Among sp3 carbanions, the +I effect of the extra methyl group makes the secondary one less stable than the primary one. So P > Q > R > S.
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