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JEE Main levelOne or more correct optionsDifficulty 2 of 3eq193

Which statements about permanganate titrations are correct?

  1. A is a suitable acid for the titration because chloride ions are not oxidised by permanganate.
  2. BIn the titration with oxalic acid the solution is warmed initially because the reaction is slow at room temperature.
  3. CThe end point is a pale pink colour that persists for about half a minute.
  4. D is not a primary standard, so its solution is standardised against oxalic acid or Mohr's salt.

Answer: B, C, D

Permanganate solutions contain and decompose slowly, so they are standardised. The oxalate reaction is slow at first (warming and autocatalysis by ). Chloride is oxidised by permanganate, so must not be used.
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