JEE Advanced levelSingle correct optionDifficulty 3 of 3ev093
In the polar lower stratosphere the cycle is: 2Cl+2OX32ClO+2OX2; ClO+ClOClX2OX2; ClX2OX2Cl+ClOO; ClOOCl+OX2. The net reaction and the number of chlorine atoms regenerated per cycle are
A2OX33OX2; 4 Cl atoms
B3OX34OX2+O; 2 Cl atoms
C2OX33OX2; 2 Cl atoms
DOX3+O2OX2; 1 Cl atom
Answer: C
Step 1 uses 2 ozone and gives 2 ClO + 2 OX2. The two ClO form ClX2OX2, which gives Cl + ClOO, and ClOO gives Cl + OX2. Totals: 2 OX3 consumed, 2+1=3OX2 formed, so 2OX33OX2. Two Cl atoms used in step 1 are regenerated as Cl + Cl.