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JEE Main levelSingle correct optionDifficulty 2 of 3ev081

In the stratospheric photolysis breaks a C-Cl bond and not a C-F bond. Taking C-Cl as about and C-F as about , the reason is that

  1. Afluorine atoms are larger than chlorine atoms
  2. BC-F bonds are non-polar
  3. Cthe weaker C-Cl bond can be broken by the available UV photons while the stronger C-F bond cannot
  4. Dchlorine is more electronegative than fluorine

Answer: C

A photon must supply at least the bond energy. The UV available in the stratosphere can break the weaker C-Cl bond, giving and Cl, but is not energetic enough for C-F bonds.
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