JEE Main levelSingle correct optionDifficulty 2 of 3ev081
In CFX2ClX2 the stratospheric photolysis breaks a C-Cl bond and not a C-F bond. Taking C-Cl as about 340kJmol−1 and C-F as about 485kJmol−1, the reason is that
Afluorine atoms are larger than chlorine atoms
BC-F bonds are non-polar
Cthe weaker C-Cl bond can be broken by the available UV photons while the stronger C-F bond cannot
Dchlorine is more electronegative than fluorine
Answer: C
A photon must supply at least the bond energy. The UV available in the stratosphere can break the weaker C-Cl bond, giving CFX2Cl and Cl, but is not energetic enough for C-F bonds.