JEE Main levelSingle correct optionDifficulty 2 of 3ec153
Which statement about the Leclanche dry cell is incorrect?
AThe zinc container acts as the anode
BA graphite rod surrounded by a paste of MnOX2 and carbon acts as the cathode
CThe electrolyte is a moist paste of NHX4Cl and ZnClX2
DThe cell can be recharged by passing current in the reverse direction
Answer: D
Anode: ZnZnX2++2eX−; cathode: MnOX2+NHX4X++eX−MnO(OH)+NHX3; the electrolyte is the NHX4Cl/ZnClX2 paste, so (A), (B) and (C) are correct. The dry cell is a primary cell: the ammonia formed is taken up as [Zn(NHX3)X2]X2+ and the reactions are not reversible, so it cannot be recharged. Statement (D) is incorrect.