JEE Main levelSingle correct optionDifficulty 2 of 3ec150
A copper plating cell is connected in series with a silver coulometer. During a run, 3.24g of silver is deposited in the coulometer and 0.762g of copper is deposited in the plating cell. The current efficiency of copper deposition is (Ag = 108, Cu = 63.5)
A75%
B80%
C85%
D90%
Answer: B
Silver deposited =3.24/108=0.0300mol, so 0.0300mol of electrons passed through both cells. Theoretical copper =0.0150×63.5=0.9525g. Efficiency =0.95250.762×100=80.0%.