JEE Main levelNumerical answerDifficulty 2 of 3ec144
A current of 2.00A is passed through aqueous ZnSOX4 for 1930s and 1.14g of zinc is deposited at the cathode. Find the current efficiency in percent (nearest integer). Take Zn = 65, F=96500Cmol−1.
Numerical answer type, answer in %, tolerance 1.
Answer: 88 %
Charge Q=2.00×1930=3860C=0.0400mol of electrons. Theoretical zinc (ZnX2++2eX−Zn) =0.0200×65=1.30g. Current efficiency =1.301.14×100=87.7%≈88%. The rest of the charge is lost mainly to hydrogen evolution.