NEET levelSingle correct optionDifficulty 1 of 3ec080
For a metal electrode MX2+/M at 298 K, the electrode potential is plotted against log[MX2+]. The slope of the straight line obtained is (take 2.303RT/F=0.0591V)
A+0.0591V per unit of log[MX2+]
B+0.0296V per unit of log[MX2+]
C−0.0296V per unit of log[MX2+]
D+0.118V per unit of log[MX2+]
Answer: B
Nernst equation for MX2++2eX−M: E=E∘+20.0591log[MX2+]. The plot of E against log[MX2+] is a straight line with positive slope 0.0591/2=0.02955≈0.0296V and intercept E∘.