JEE Advanced levelSingle correct optionDifficulty 3 of 3df201
A yellow acidic solution of CeX4+ is treated with excess FeX2+ in dilute sulfuric acid. The cerium species present at the end, and its magnetic character, are
ACeX4+ with 4f0; unchanged
BCeX3+ with 4f0; diamagnetic
CCeX3+ with 4f1; paramagnetic with one unpaired electron
DCeX2+ with 4f2; paramagnetic with two unpaired electrons
Answer: C
CeX4+ oxidises FeX2+ to FeX3+ and is itself reduced: CeX4++FeX2+CeX3++FeX3+ (charge 6 on both sides). Ce is 4f15d16s2, so CeX3+ is 4f1 with one unpaired electron, hence paramagnetic.