MolSynapsequestion bank
MolSynapse / Question bank / d- and f-Block Elements / Lanthanoids and lanthanoid contraction
JEE Advanced levelSingle correct optionDifficulty 3 of 3df201

A yellow acidic solution of is treated with excess in dilute sulfuric acid. The cerium species present at the end, and its magnetic character, are

  1. A with ; unchanged
  2. B with ; diamagnetic
  3. C with ; paramagnetic with one unpaired electron
  4. D with ; paramagnetic with two unpaired electrons

Answer: C

oxidises to and is itself reduced: (charge 6 on both sides). Ce is , so is with one unpaired electron, hence paramagnetic.
Practice d- and f-Block Elements More on Lanthanoids and lanthanoid contraction

More questions on Lanthanoids and lanthanoid contraction