JEE Advanced levelSingle correct optionDifficulty 3 of 3df199
A lanthanoid has atomic number 64 and the ground-state configuration [Xe]4f75d16s2. The spin-only magnetic moment (in BM) of its tripositive ion is closest to
A8.94
B6.93
C5.92
D7.94
Answer: D
The three electrons lost are 5d1 and 6s2, so the ion is 4f7 with n = 7 unpaired electrons. Spin-only μ=n(n+2)=63=7.94 BM. Values 6.93, 5.92 and 8.94 correspond to n = 6, 5 and 8.