JEE Main levelSingle correct optionDifficulty 2 of 3df188
The decrease in size across the actinoid series is, element to element, greater than that across the lanthanoids. The reason generally given is that
A5f electrons shield the nuclear charge even less effectively than 4f electrons
Bthe actinoids have fewer electrons in the outer shell
C5f electrons shield the nuclear charge more effectively than 4f electrons
Dthe actinoids are all radioactive
Answer: A
The 5f orbitals are more diffuse and shield the increasing nuclear charge worse than 4f orbitals. Effective nuclear charge therefore grows faster and the actinoid contraction is more pronounced.