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JEE Advanced levelSingle correct optionDifficulty 3 of 3df048

Which statement correctly explains why interstitial carbides such as are harder and have much higher melting points than tungsten metal, while still conducting electricity?

  1. AC atoms in the voids add M-C covalent bonding and hinder slip of metal layers, while the delocalised metal electrons are retained
  2. Bcarbon forms a molecular lattice with weak van der Waals forces, which raises hardness
  3. Ccarbon atoms donate their electrons to tungsten, which removes all free electrons
  4. Dthe metal lattice is destroyed and replaced by a discrete ionic lattice of and

Answer: A

The small C atoms occupy interstitial sites without changing the metal lattice, so the metallic electron sea remains and conduction is retained. The extra M-C bonding and blocked slip planes increase hardness and melting point. The other options describe ionic or molecular solids, which do not conduct like metals.
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