JEE Main levelSingle correct optionDifficulty 2 of 3df013
Assertion (A): MnX2+ does not get oxidised to MnX3+ in aqueous solution, as E∘(MnX3+/MnX2+)=+1.5V.
Reason (R): MnX2+ has the stable half-filled 3d5 configuration.
ABoth A and R are true and R is the correct explanation of A
BBoth A and R are true but R is not the correct explanation of A
CA is true but R is false
DA is false but R is true
Answer: A
The large positive E∘ means MnX3+ is a strong oxidant and MnX2+ is hard to oxidise, so A is true. Removing an electron from d5 gives d4, losing exchange energy, which is exactly why MnX2+ is stable. R is true and explains A.