JEE Advanced levelSingle correct optionDifficulty 3 of 3cc208
Assertion: Ni(CO)X4 is paramagnetic with two unpaired electrons because it is a tetrahedral d8 complex. Reason: In Ni(CO)X4 nickel is in the zero oxidation state and its valence electrons are arranged as 3d10.
ABoth Assertion and Reason are true, and the Reason is the correct explanation of the Assertion
BBoth Assertion and Reason are true, but the Reason is not the correct explanation of the Assertion
CAssertion is true but Reason is false
DAssertion is false but Reason is true
Answer: D
Ni(0) has the configuration 3d10 (the 4s2 electrons are moved into 3d by the strong-field CO), so there are no unpaired electrons and the complex is diamagnetic, with sp3 hybridisation. The Assertion is false, the Reason is true.