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JEE Advanced levelSingle correct optionDifficulty 3 of 3cc208

Assertion: is paramagnetic with two unpaired electrons because it is a tetrahedral complex. Reason: In nickel is in the zero oxidation state and its valence electrons are arranged as .

  1. ABoth Assertion and Reason are true, and the Reason is the correct explanation of the Assertion
  2. BBoth Assertion and Reason are true, but the Reason is not the correct explanation of the Assertion
  3. CAssertion is true but Reason is false
  4. DAssertion is false but Reason is true

Answer: D

Ni(0) has the configuration (the electrons are moved into by the strong-field ), so there are no unpaired electrons and the complex is diamagnetic, with hybridisation. The Assertion is false, the Reason is true.
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