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JEE Main levelOne or more correct optionsDifficulty 2 of 3cc192

Which statements about bonding in metal carbonyls are correct?

  1. ACO donates a lone pair on carbon to a vacant metal orbital
  2. Bfilled metal orbitals donate into the orbitals of CO
  3. Cback-donation strengthens the C-O bond
  4. Dback-donation strengthens the M-C bond

Answer: A, B, D

The carbon lone pair forms the bond to the metal (A) and filled metal orbitals back-donate into (B). Back-donation adds electrons to an antibonding orbital, so it weakens, not strengthens, C-O (C is false). It adds character to the M-C bond, strengthening and shortening it (D). Correct: A, B, D.
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