JEE Advanced levelSingle correct optionDifficulty 3 of 3cc163
Which statement about the square planar complex [Pt(NHX3)(py)ClBr] (py = pyridine) is correct?
AIt has 3 geometrical isomers, all paramagnetic with two unpaired electrons.
BIt has 3 geometrical isomers, each of which exists as a pair of enantiomers.
CIt has 3 geometrical isomers, all diamagnetic and none optically active.
DIt has 2 geometrical isomers, one of which is optically active.
Answer: C
Pt(II) is d8 and in a square planar field all electrons are paired, so every isomer is diamagnetic. Mabcd has 3 geometrical isomers. Each one is planar, so the molecular plane is a mirror plane, and none is optically active.