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JEE Advanced levelSingle correct optionDifficulty 3 of 3cc163

Which statement about the square planar complex (py = pyridine) is correct?

  1. AIt has 3 geometrical isomers, all paramagnetic with two unpaired electrons.
  2. BIt has 3 geometrical isomers, each of which exists as a pair of enantiomers.
  3. CIt has 3 geometrical isomers, all diamagnetic and none optically active.
  4. DIt has 2 geometrical isomers, one of which is optically active.

Answer: C

Pt(II) is and in a square planar field all electrons are paired, so every isomer is diamagnetic. has 3 geometrical isomers. Each one is planar, so the molecular plane is a mirror plane, and none is optically active.
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