JEE Advanced levelSingle correct optionDifficulty 3 of 3cc145
The salt NiClX2⋅6NHX3 gives 2 mol of AgCl per mole with excess AgNOX3. Assuming octahedral coordination (coordination number 6) and using the spin-only formula, the magnetic moment of the complex ion in BM is
A1.73
B2.83
C0
D3.87
Answer: B
Two free chlorides and coordination number 6 give [Ni(NHX3)X6]ClX2 with Ni(II), d8. In an octahedral field d8 is t2g6eg2 whatever the field strength, so 2 unpaired electrons. μ=n(n+2)=8=2.83 BM.