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Coordination Compounds
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Colour and magnetic moment of complexes
JEE Advanced level
Numerical answer
Difficulty 3 of 3
cc073
What is the spin-only magnetic moment, in BM, of the complex ion in
K
X
3
[
Mn
(
CN
)
X
6
]
? Treat CN- as strong field. Give the answer to two decimal places.
Numerical answer type, answer in BM, tolerance 0.01.
Answer: 2.83 BM
Charge:
x
−
6
=
−
3
gives Mn(III),
d
4
. Strong-field CN- gives
t
2
g
4
e
g
0
with 2 unpaired electrons.
μ
=
2
×
4
=
8
=
2.83
BM
.
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