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JEE Advanced levelSingle correct optionDifficulty 3 of 3cc042

How many stereoisomers (geometrical plus optical) are possible for the octahedral complex ion , where en is a symmetrical bidentate ligand?

  1. A6
  2. B4
  3. C2
  4. D3

Answer: B

Treat en as a cis-spanning unit, giving an octahedron. Enumerating the arrangements gives three geometrical isomers (the two trans; the two trans; neither pair trans). The last has no mirror plane and exists as an enantiomeric pair, so the total is stereoisomers.
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