JEE Advanced levelSingle correct optionDifficulty 3 of 3el190
One litre of hard water contains 2.0×10−3 mol of CaX2+. Sodium palmitate, CX15HX31COONa (molar mass 278 g/mol), is added until every calcium ion is precipitated as calcium palmitate. The mass of sodium palmitate used up per litre is
A2.224g
B1.112g
C0.556g
D0.278g
Answer: B
Each CaX2+ ion needs two palmitate ions: 2CX15HX31COOX−+CaX2+(CX15HX31COO)X2Ca. Moles of soap = 2×2.0×10−3=4.0×10−3 mol. Mass = 4.0×10−3×278=1.112g.