JEE Main levelNumerical answerDifficulty 2 of 3ck072
A reaction 2AP is second order with −d[A]/dt=k[A]2 and k=0.032Lmol−1s−1. How long (in seconds, nearest integer) does it take for [A] to fall from 0.40molL−1 to 0.10molL−1?
Numerical answer type, answer in s, tolerance 0.5.
Answer: 234 s
Use kt=1/[A]−1/[A]0. Then t=(1/0.10−1/0.40)/0.032=(10−2.5)/0.032=234.38s, i.e. about 234 s.