JEE Advanced levelSingle correct optionDifficulty 3 of 3ck049
A zero order reaction (rate constant k0) and a first order reaction (rate constant k1) have the same initial concentration [A]0 and the same initial rate. The ratio t1/2(zero order)/t1/2(first order) is (use ln2=0.693)
A1.39
B0.50
C0.72
D1.00
Answer: C
Equal initial rates give k0=k1[A]0. Then t1/2(0)=[A]0/2k0=1/(2k1) and t1/2(1)=0.693/k1. The ratio is 0.5/0.693=0.7215≈0.72.