JEE Advanced levelSingle correct optionDifficulty 3 of 3ce200
The density of an equilibrium mixture of NX2OX4 and NOX2 is 2.70g/L at 300K and 1.00atm. Take R=0.0821Latmmol−1K−1 and M(NX2OX4)=92. The degree of dissociation of NX2OX4 is about
A0.19
B0.28
C0.38
D0.72
Answer: C
Mavg=ρRT/P=2.70×0.0821×300/1.00=66.50 g/mol. With Mavg=92/(1+α): α=92/66.50−1=0.3834, about 0.38.