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JEE Main levelSingle correct optionDifficulty 2 of 3cb193

Assertion (A): The boiling point of () is much higher than that of (). Reason (R): A water molecule can form up to four hydrogen bonds (two as donor, two as acceptor), whereas an molecule can form only about two.

  1. ABoth A and R are true and R is the correct explanation of A
  2. BBoth A and R are true but R is not the correct explanation of A
  3. CA is true but R is false
  4. DA is false but R is true

Answer: A

Both and are strongly hydrogen bonded, but water has two H atoms and two lone pairs and so builds a three-dimensional network. has one H and, in effect, forms chains, so the total hydrogen bonding per mole is smaller. Hence A and R are both true and R explains A.
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