MolSynapsequestion bank
MolSynapse / Question bank / Chemical Bonding / Bond length, bond angle and bond order comparisons
JEE Advanced levelSingle correct optionDifficulty 3 of 3cb103

Assertion: The H-N-H bond angle in is greater than the H-P-H bond angle in . Reason: Nitrogen is more electronegative than phosphorus, so the bonding pairs lie closer to nitrogen and repel each other more strongly.

  1. ABoth Assertion and Reason are true and Reason is the correct explanation of Assertion
  2. BBoth Assertion and Reason are true but Reason is not the correct explanation of Assertion
  3. CAssertion is true but Reason is false
  4. DAssertion is false but Reason is true

Answer: A

Both statements are true: the angles are about and . Bonding pairs close to the small, more electronegative N atom repel strongly, which opens the angle. On P the pairs lie farther away, repulsion is weak and the lone pair shrinks the angle towards .
Practice Chemical Bonding More on Bond length, bond angle and bond order comparisons

More questions on Bond length, bond angle and bond order comparisons