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JEE Advanced levelSingle correct optionDifficulty 3 of 3co154

Phenyl methyl ketone is treated successively with (i) in methanol, (ii) excess and with warming, and (iii) dilute . The organic acid formed is

  1. Aphenylethanoic acid
  2. B1-phenylethan-1-ol
  3. Cbenzaldehyde
  4. Dbenzoic acid

Answer: D

gives 1-phenylethan-1-ol, . Iodine and base oxidise this to and then cleave it by the haloform reaction to and . Acidification gives benzoic acid.
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