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Aldehydes, Ketones and Carboxylic Acids
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Aldol, Cannizzaro, Perkin, Claisen and related condensations
JEE Advanced level
Single correct option
Difficulty 3 of 3
co090
Ethanal is warmed with dilute NaOH to give X. X is then hydrogenated with excess
H
X
2
over Ni at high pressure to give Y. Y is
A
butanal
B
but-2-en-1-ol
C
butan-2-ol
D
butan-1-ol
Answer: D
Aldol condensation of ethanal on warming gives X = but-2-enal. Excess
H
X
2
/Ni reduces both C=C and C=O. Y is
CH
X
3
CH
X
2
CH
X
2
CH
X
2
OH
, butan-1-ol.
Practice Aldehydes, Ketones and Carboxylic Acids
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