JEE Advanced levelSingle correct optionDifficulty 3 of 3co089
Acetophenone and benzaldehyde are warmed with NaOH in ethanol until dehydration is complete to give P. P is then shaken with exactly one mole of HX2 over Pd/C at room temperature to give Q. Q is
A1,3-diphenylpropan-1-ol
B1,3-diphenylpropan-1-one
C1,3-diphenylprop-2-en-1-ol
D3-hydroxy-1,3-diphenylpropan-1-one
Answer: B
Claisen-Schmidt condensation gives P, chalcone CX6HX5CH=CHCOCX6HX5. With one mole of HX2 over Pd/C, the isolated C=C is reduced much faster than the aryl ketone or the rings. Q is CX6HX5CHX2CHX2COCX6HX5, 1,3-diphenylpropan-1-one.