JEE Main levelSingle correct optionDifficulty 2 of 3co052
Ethanal is dissolved in excess methanol and dry HCl gas is passed through the solution. The compound that is isolated is
A1-methoxyethan-1-ol
B2-methoxyethan-1-ol
C1,1-dimethoxyethane
Dmethoxyethane
Answer: C
Under acid catalysis the aldehyde first forms a hemiacetal, CHX3CH(OH)OCHX3, which is unstable. With excess alcohol, the hemiacetal is converted to the acetal CHX3CH(OCHX3)X2.