JEE Advanced levelOne or more correct optionsDifficulty 3 of 3co005
Which of the following statements about nucleophilic addition to carbonyl compounds are correct?
A4-nitrobenzaldehyde is more reactive than benzaldehyde
BCHX3COCHX3 is more reactive than (CHX3)X3CCOC(CHX3)X3
Cbenzaldehyde is more reactive than ethanal
DHCHO is more reactive than CHX3CHO
Answer: A, B, D
Steric and inductive effects explain the first two, and the nitro group raises electrophilicity in the third. In benzaldehyde, resonance with the ring lowers the positive charge on carbon, so it is less reactive than ethanal.