JEE Advanced levelOne or more correct optionsDifficulty 3 of 3co011
Which of the following statements about acetals and ketals are correct?
AThey are stable to aqueous NaOH
BThey react with CHX3MgBr to give tertiary alcohols
CThey are formed by acid catalysis with removal of water
DDilute aqueous acid hydrolyses them to the carbonyl compound
Answer: A, C, D
Acetals lack an electrophilic carbonyl carbon, so they are inert to bases and Grignard reagents. Their formation is reversible and acid catalysed, and excess water with acid hydrolyses them.