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Aldehydes, Ketones and Carboxylic Acids
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Preparation of aldehydes and ketones
JEE Main level
Single correct option
Difficulty 2 of 3
co002
Propanenitrile is treated with an ether solution of methylmagnesium bromide and then with dilute aqueous acid. The major organic product is
A
propan-2-ol
B
butan-2-one
C
pentan-2-one
D
butan-2-ol
Answer: B
CH
X
3
X
−
adds to the nitrile carbon to give an imine salt
CH
X
3
CH
X
2
C
(
CH
X
3
)
=
NMgBr
. Hydrolysis converts
C
=
N
into
C
=
O
, giving
CH
X
3
CH
X
2
COCH
X
3
.
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