JEE Advanced levelOne or more correct optionsDifficulty 3 of 3bm138
An enzyme-catalysed reaction has Ea=80kJmol−1 without the enzyme and 50kJmol−1 with it, at 300K. Take R=8.314Jmol−1K−1, equal pre-exponential factors, and the enzyme lowering the reverse activation energy by the same amount. Select the correct statements.
AThe forward rate constant increases by more than a factor of 105.
BThe forward rate constant increases by less than a factor of 104.
CThe rate constant of the reverse reaction also increases by the same factor as the forward one.
DThe enthalpy change of the reaction becomes 30kJmol−1 more negative.
Answer: A, C
The enhancement is exp(30000/(8.314×300))=e12.03≈1.7×105, so more than 105. Lowering both barriers by 30 kJ speeds up the reverse reaction by the same factor and leaves ΔH unchanged.