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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3bm138

An enzyme-catalysed reaction has without the enzyme and with it, at . Take , equal pre-exponential factors, and the enzyme lowering the reverse activation energy by the same amount. Select the correct statements.

  1. AThe forward rate constant increases by more than a factor of .
  2. BThe forward rate constant increases by less than a factor of .
  3. CThe rate constant of the reverse reaction also increases by the same factor as the forward one.
  4. DThe enthalpy change of the reaction becomes more negative.

Answer: A, C

The enhancement is , so more than . Lowering both barriers by 30 kJ speeds up the reverse reaction by the same factor and leaves unchanged.
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